Pabrik Kaprolaktam dari Sikloheksanon dan Hidroksilamin Sulfat dengan Proses Rearrangement Beckmann Kapasitas 100.000 Ton/Tahun

Safira, Lutfia Rima (2025) Pabrik Kaprolaktam dari Sikloheksanon dan Hidroksilamin Sulfat dengan Proses Rearrangement Beckmann Kapasitas 100.000 Ton/Tahun. Undergraduate thesis, UPN "VETERAN" JAWA TIMUR.

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Abstract

Caprolactam Plant from Cyclohexanone and Hydroxylamine Sulfate with Beckmann Rearrangement Process with Capacity of 100,000 Ton/Year will be established in Modern Industrial Area Cikande, Jl. Raya Jakarta Serang KM. 68 Cikande, Nambo Ilir, Kec. Kibin, Serang Regency, Banten 42186. This Caprolactam Plant uses a continuous operating system for 24 hours a day with 330 working days and 220 employees. This plant uses Cyclohexanone raw materials obtained from PT. Chandra Asri Petrochemical located in Cilacap, Hydroxylamine Sulfate obtained from PT. Lotte Chemical Titan located in Cilegon, Ammonium Hydroxide obtained from PT. Pupuk Kujang Cikampek located in Karawang, Sulfuric acid obtained from PT. Indonesian Acid Industry located in Cakung, and Toluene obtained from PT. Stryrindo Mono Indonesia located in Serang. Caprolactam can be used as raw material for Nylon-6, Nylon filament yarn, nylon-6 resin, polyurethane, and amino caproic acid. While from this process, a by-product will be produced, namely ammonium sulfate which can be used as agricultural fertilizer (fertilizer), as a buffer in chemical solutions, textile dyes, and so on. The production process used in this factory is the Beckmann Rearrangement process. There are several stages that take place, the first is the amoximation reaction between cyclohexanone and hydroxylamine sulfate and 30% ammonium hydroxide using a stirred tank flow reactor at a temperature of 115 ̊C and a pressure of 2 atm which will produce cyclohexanone oxime and a by-product in the form of ammonium sulfate. Furthermore, the Beckmann Rearrangement reaction is carried out, namely cyclohexanone oxime will be added with a sulfuric acid catalyst using a stirred tank flow reactor at a temperature of 115 ̊C and a pressure of 2 atm which will produce caprolactam. After that, the caprolactam which still contains sulfuric acid will be neutralized using a stirred tank flow reactor at a temperature of 80 ̊C and a pressure of 1 atm which will produce caprolactam and a by-product of ammonium sulfate.

Item Type: Thesis (Undergraduate)
Contributors:
ContributionContributorsNIDN/NIDKEmail
Thesis advisorSusilowati, TitiNIDN196008011987032008UNSPECIFIED
Subjects: T Technology > TP Chemical technology
T Technology > TP Chemical technology > TP155 Chemical engineering
Divisions: Faculty of Engineering > Departement of Chemical Engineering
Depositing User: Lutfia Rima Safira
Date Deposited: 23 Jun 2025 03:50
Last Modified: 23 Jun 2025 03:50
URI: https://repository.upnjatim.ac.id/id/eprint/39026

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