LAPORAN HASIL PENELITIAN SINTESIS BIODIESEL DARI CRUDE PALM OIL (CPO) OFF GRADE DENGAN KATALIS CaO TERIMPREGNASI (NH₄)₂CO₃

Junaidi, Sabrina Nayla (2025) LAPORAN HASIL PENELITIAN SINTESIS BIODIESEL DARI CRUDE PALM OIL (CPO) OFF GRADE DENGAN KATALIS CaO TERIMPREGNASI (NH₄)₂CO₃. Undergraduate thesis, UPN Veteran Jawa Timur.

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Abstract

This work explores the production of biodiesel from off-grade crude palm oil (CPO) by employing calcium oxide (CaO) modified through impregnation with ammonium carbonate ((NH₄)₂CO₃) as a solid base catalyst. Incorporating ammonium carbonate notably altered the physicochemical characteristics of CaO; the untreated material possessed a surface area of only 8.242 m²/g, whereas the impregnated catalyst reached 96.390 m²/g, supplying a substantially larger number of accessible catalytic sites for transesterification. The biodiesel generated under the tested operating conditions met key fuel quality indicators, with flash points exceeding 180 °C, acid numbers between 0.2 and 0.3 mg KOH/g, and kinematic viscosity values ranging from 3 to 7 mm²/s. The maximum yield, 89.03%, was achieved using 2.5 wt% catalyst and a reaction duration of 3.5 hours. The fuel also exhibited a cetane number above 65, reflecting strong ignition behavior and favourable combustion performance. Overall, the findings show that CaO impregnated with (NH₄)₂CO₃ considerably improves the catalytic efficiency of the transesterification process and allows off-grade, high-FFA CPO to be converted effectively into biodiesel. This approach presents a technically feasible and potentially more cost-effective and sustainable method for producing biodiesel from lower-quality palm oil resources.

Item Type: Thesis (Undergraduate)
Contributors:
ContributionContributorsNIDN/NIDKEmail
Thesis advisorSaputro, Erwan AdiNIDN0010048001erwanadi.tk@upnjatim.ac.id
Subjects: T Technology > T Technology (General)
T Technology > TP Chemical technology
T Technology > TP Chemical technology > TP155 Chemical engineering
Divisions: Faculty of Engineering > Departement of Chemical Engineering
Depositing User: Sabrina Nayla Junaidi
Date Deposited: 04 Dec 2025 04:42
Last Modified: 04 Dec 2025 04:42
URI: https://repository.upnjatim.ac.id/id/eprint/47697

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