Removal Ion Pb2+ dari Larutan Pb(NO3)2 Menggunakan Geopolimer Berbasis Abu Sekam Padi dan Metakaolin

Cahyani, Fatikhah (2026) Removal Ion Pb2+ dari Larutan Pb(NO3)2 Menggunakan Geopolimer Berbasis Abu Sekam Padi dan Metakaolin. Undergraduate thesis, UPN Veteran Jawa Timur.

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Abstract

Heavy metal contamination in aquatic environments is a serious environmental issue due to its toxicity, persistence, and tendency to accumulate in organisms. One promising approach to address this problem is adsorption using aluminosilicate-based geopolymers. This study aimed to evaluate the ability of rice husk ash and metakaolin-based geopolymers to remove Pb²⁺ ions and to investigate the effects of Si/Al molar ratio and NaOH concentration on removal efficiency and adsorption capacity, and identify the adsorption mechanism of Pb²⁺ ions. Geopolymers were synthesized using rice husk ash as a silica source and metakaolin as an alumina source with varying Si/Al molar ratios and NaOH concentrations. The synthesized geopolymers were characterized using SEM-EDX and FTIR, while their adsorption performance was evaluated based on Pb²⁺ removal efficiency and adsorption capacity. The results demonstrated that the geopolymer was successfully synthesized and showed potential as an effective adsorbent for Pb²⁺ removal. SEM-EDX and FTIR analyses confirmed the formation of an aluminosilicate structure and indicated that Pb²⁺ adsorption involved ion-exchange mechanisms and interactions with active functional groups on the geopolymer surface. Variations in the Si/Al molar ratio and NaOH concentration affected the removal efficiency and adsorption capacity of the geopolymer. The optimum adsorption condition was achieved at a Si/Al molar ratio of 4.2 and a NaOH concentration of 10 M, resulting in an adsorption capacity of 7.94 mg/g and a removal efficiency of 99.83%. Keywords: geopolymer, rice husk ash, metakaolin, adsorption, Pb²⁺.

Item Type: Thesis (Undergraduate)
Contributors:
ContributionContributorsNIDN/NIDKEmail
Thesis advisorMuljani, SrieNIDN0012116111sriemuljani.tk@upnjatim.ac.id
Subjects: T Technology > T Technology (General)
T Technology > TP Chemical technology
T Technology > TP Chemical technology > TP155 Chemical engineering
Divisions: Faculty of Engineering > Departement of Chemical Engineering
Depositing User: Fatikhah Cahyani
Date Deposited: 01 Sep 2026 02:48
Last Modified: 01 Sep 2026 03:30
URI: https://repository.upnjatim.ac.id/id/eprint/59074

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